By 鈴木, 基之, 1941- 鈴木, 基之, ; Motoyuki Suzuki
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E Sohn, 159th ACS Annual Meeting, Denver(1987). Suzukl, M . and T FUJI],Roc 4th APCChE '87, 675, S~ngapore(1987). Suzukl, M and K Chlhara, WaferResearch. 22,627 (1988). Suzuk~,T , K. lshlgak~and N. Ayuzawa, Chem. fig. 143 (1985). Karserfan. Kcro f o Ouyou (Acttvated Carbon. FundarnenfaLr and Applrcanons), Kodansha, Tokyo (1975) ( ~ n Japanese) Zeora~to to sono R ~ y o u Henshuu Ilnka~, Zeoraifo f o sono Riyou (Zeolite and rfs Applrcafions), Glhodo, Tokyo (1967) (in Japanese). Adsorption Equilibrium In practical operations, maximum capacity of adsorbent cannot be fully utilized because of mass transfer effects involved in actual fluid-solid contacting processes.
Pressure. (Reproduced with permission by Horvath, G. and Kawazoc. , J. Ckm fig Jqpms 16,473 (1983)). Effective pore size (nm) Fig. 18. Effective pore size distributions of carbon molecular sieves calculated by Horvath-Kawazoe method. (Reproduced with permission by Horvath, G. , J. Chem. fig. Japun. 16,474 (1983)). C. molecular probe method As is understood from Fig. 9, for small pores which have molecular sieving abilities, it is not possible to determine pore size distribution by nitrogen adsorption method.
3-47) can be determined analytically. For instance, if the Freundlich equation can be applied in a wide range, then the integral becomes which greatly simplifies the procedure. But it should be kept in mind that unless single-component isotherms especially for the weaker component are determined in a wide range of amounts adsorbed, this simplified treatment may result in considerable deviation. The IAS model is practical for predicting binary isotherms from singlecomponent isotherm data. As an example, isotherms of propane and butane on activated carbon are shown in Fig.